The team were celebrating their second goal against Ukraine in the Euro 2020 quarter-finals when Rice was caught by her skipper.
After Harry Maguire doubled England’s advantage, Rice was the first man to catch up with the Manchester United defender as he celebrated his goal.
Kane was next to the party, jumping on Maguire and Rice and accidentally throwing the latter into a headache.
The West Ham star was held back by the captain for a few seconds before the adrenaline wore off and Rice could smile again.
BBC Sport then shared a video of the hilarious incident on Twitter – and the 22-year-old joined in the fun by quoting the tweet.
Rice joked, “Why always me? “
The England midfielder will be hoping Kane will give him another lead in the team’s semi-final against Denmark at Wembley.
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Gareth Southgate’s side will be full of confidence after beating Ukraine 4-0 with Kane scoring a brace in Rome.
Rice started every Euro 2020 game and put in a great quarterfinal performance, earning a 7/10 rating from SunSport.
The former Republic of Ireland international has been linked with a move this summer and has reportedly rejected two contract offers from the Hammers.
Reports suggest Manchester United are interested in signing Rice after agreeing a fee with Borussia Dortmund for England winger Jadon Sancho.
And the youngster has been linked with Chelsea – the club he left in 2014 to join West Ham academy.
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